Ceramic Materials for Energy Applications
Dr. Nina Orlovskaya's Publications
- Lukich, S., Carpenter, C., Orlovskaya, N., Micro-Raman characterization of cubic and rhombohedral ?-Sc0.1Ce0.01ZrO2 ceramics, J. Power Sources, accepted, 2009.
- Gangopadhayay, S., Inerbaev, T., Masunov, A., Altilio, D., Orlovskaya, N., Structural characterization combined with the first principles simulations of barium/strontium cobaltite/ferrire as promising material for Solid Oxide Fuel Cells cathodes and high temperature oxygen permeation membranes, ACS Applied Materials and Interfaces, 1, 7, 1512-1519, 2009.
- Viola, G., Verbulo, D., Orlovskaya, N., Reece, M.J., Time dependent
behavior of ferroelectric/ferroelastic perovskites, J. Mater. Sci. Tech., accepted, 2009.
- Jiang, T., Wang, Y., Wang, Y., Orlovskaya, N., An, L., Quantitative Raman analysis of free carbons in polymer-derived ceramics, J. Am. Ceram. Soc., 92, 10, 2455-2458, 2009.
- Johnson, C., Orlovskaya, N., Coratolo, A., Cross, C., Wu, J., Gemmen, R., Liu, X.,
The effect of coating crystallization and substrate impurities on magnetron sputtered
doped LaCrO3 coatings for metallic solid oxide fuel cell interconnects, Int. Journal of
Hydrogen Energy, 34, 5, 2408-2415, 2009.
- Yarmolenko, S., Sankar, J., Bernier, N., Klimov, M., Kapat, J., Orlovskaya, N.,
Phase stability and sintering behavior of 10mol% Sc2O3-1mol%CeO2-ZrO2, Journal
of Fuel Cells Science and Technology, 6, 2, 021007, 2009.
- Lugovy, M., Slyunyayev, V., Orlovskaya, N., An ultimate state of layered
cantilever sensors under bending: a simplified evaluation, Mechanics of Advanced
Materials and Structure, accepted, 2009.
- Orlovskaya, N., Lugovy, M., Carpenter, C., Pathak, S., Steinmetz, D.,
Lara-Curcio, E., Klemenz,C., Radovic, M., On thermal and vibrational properties
of LaGaO3 single crystals, Acta Materialia, 57, 2984-2992, 2009.
- Orlovskaya, N., Lugovy, M., Verbulo, D., Reece, M.J., Dual ferroelasticity
of lanthanum chromium-based multicomponent solid solution perovskite, Scripta Materialia,
60, 9, 783-786, 2009.
- Pathak, S., Steinmetz, D., Kuebler, J., Payzant, A., Orlovskaya, N.,
Mechanical behavior of La0.8Sr0.2Ga0.8Mg0.2O3 perovskites, Ceram. International,
35, 3, 1235-1241, 2009.
- Lugovy, M., Slyunyayev, V., Orlovskaya, N., Verbylo, D., Reece, M.,
Room temperature creep of LaCoO3 based perovskites: equilibrium strain
under compression, Phys. Rev. B, 78, 024107, 2008.
-
Ghosh, D., Subhash, G., Orlovskaya, N., Scratch-induced residual
stress measurements within SiC particles in a ZrB2 – SiC composite using micro-Raman
spectroscopy, Acta Mater., 56, 5345-5354, 2008.
- Orlovskaya, N., Lugovy, M., Kuebler, J., Yarmolenko, S., Sankar, J., Effect of
rolling and hot pressing on mechanical properties of boron carbide based ceramics,
J. Mater. Sci., 43, 17, 5942-5947, 2008.
- Orlovskaya, N., Lugovy, M., Pathak, S., Steinmetz, D., Lloyd, J., Fegely,
L., Radovic, M., Payzant, E.A., Lara-Curzio, E., Allard, L., Kuebler, J.,
Thermal and mechanical properties of LaCoO3 and La0.8Ca0.2CoO3
perovskites, J. Power Sources, 182, 230-239, 2008.
- Lukich, S., Carpenter, Orlovskaya, N., Temperature and stress
assisted cubic to rhombohedral phase transition in Sc0.1Ce0.01ZrO2
electrolyte ceramics, 33rd International Conference on Advance Ceramics
and Composites, Daytona Beach, submitted, 2009.
- Orlovskaya, N., Sleiti, A., Naimaster, E., Bonadies, M., Kapat, J., and
Johnson, C., Impact of temperature and porosity on Sc2O3-CeO2-ZrO2 Intermediate
Temperature Solid Oxide Fuel Cell performance, 47th AIAA Aerospace Sciences
Meeting, AIAA-2009-1207, Orlando, FL, 2009.
- Gangopadhayay, S., Masunov, A.E., Mesit, J., Guha, R., Kapat, J., Orlovskaya,
N., Multiscale simulations of vacancy diffusion coefficients in of Barium/Strontium
Ferrate/Cobaltate (BSCF) as a promising material for solid oxide fuel cell, The
Fourth International Conference on Multiscale Materials Modeling. October 27-31, 2008.
- S. Ganopadhyay, T. Inerbaev, A. E. Masunov, D. Altilio, N. Orlovskaya,
J. Mesit, R. Guha, A. Sleiti, J. Kapat. Density functional theory and multiscale
simulations combined with spectroscopic study of Barium/Strontium
Ferrate/Cobaltate (BSCF) as a promising material for solid oxide fuel cell (SOFC),
17th Conference on Current Trends on Computational Chemistry. October 31-November 1, 2008.
- Radovic, M., Speakman, S.A., Allard, L.F., Payzant, E.A., Lara-Curzio,
E., Kriven,W., Lloyd, J., Fegely, L., Orlovskaya, N., Thermal properties and
structural stability of LaCoO3 in reducing and oxidizing environments, J. Power Sources,
184, 1, 77-83 2008.
- Ghosh, D.,Subhash, G., Orlovskaya, N., Scratch-induced deformation and
residual stress in a zirconium diboride-silicon carbide composite, 32nd International
Conference on Advance Ceramics and Composites, Daytona Beach, published, 2008.
- Ghosh, D., Subhash, G., Orlovskaya, N., Scratch-induced residual
stress measurements within SiC particles in a ZrB2 – SiC composite using
micro-Raman spectroscopy, Phys. Rev. B, submitted, 2008.
- Rosten,
R., Swanson, M., Kuebler, J., Kapat, J., Orlovskaya, N.,
Characterization of (La0.9Sr0.1)0.95Cr0.85Mg0.1Ni0.05O3
perovskite ceramics for a perovskite related membrane
reactor, in Solid-State Ionics, edited by E. Traversa,
T. Armstrong, C. Masquelier, and Y. Sadaoka (Mater. Res.
Soc. Symp. Proc.972, Warrendale, PA, 2007), 0972-AA02-07.
- Zevalkink,
A., Hunter, A., Swanson, M., Johnson, C., Kapat, J., Orlovskaya,
N., Processing and characterization of SC2O3-CeO2-ZrO2
electrolyte based Intermediate Temperature Solid Oxide
Fuel Cells, in Solid-State Ionics, edited by E. Traversa,
T. Armstrong, C. Masquelier, and Y. Sadaoka (Mater. Res.
Soc. Symp. Proc.972, Warrendale, PA, 2007), 0972-AA03-04.
- Pathak, S., Kalidindi, S., Klemenz, C., Orlovskaya,
N., Mechanical properties of LaGaO3 single
crystals by indentation. Part II. Indentation by spherical
indenters, Mat. Sci. Eng. A., submitted, 2007.
- Kuebler,
J., Blugan, G., Lugovy, M., Slyunyayev, V., Orlovskaya,
N., Dobedoe, R., Development of failure tolerant multilayer
silicon nitride ceramics: Review from macro to micro layered
structures, Key Engineering Materials, 333, 117-126, 2007.
- Orlovskaya, N., Lugovy, M., Kuebler, J.,
Yarmolenko, S., Sankar, J., Effect of rolling and hot
pressing on mechanical properties of boron carbide based
ceramics, J. Mat. Sci, submitted 2007.
- Orlovskaya, N.,
Coratolo, A., Lugovy, M., Johnson, C., Gemmen, R., Structural
evolution of La-Cr-O thin films: Part I. Microstructure
and phase development, Thin Solid Films, 515, 1741-1747,
2006.
- Chi, M., Browning,
N., Orlovskaya, N., Microstructural evolution of protective
La-Cr-O films studied by Transmission Electron Microscopy,
J. Solid State Electrochemistry, 10, 659-662, 2006.
- Orlovskaya, N.,
Anderson, H., Brodnikovskyy, M., Lugovy, M., Reece, M.,
Inelastic deformation behaviour of La0.6Sr0.4FeO3
perovskite, J. Appl. Phys., 100, 026102, 2006.
- Isupova,
L., Obyskalova, E., Rogov, V., Tsybulya, S., Dovlitova,
L., Burgina, E., Ischenko, A., Zaikovskii, Sadykov, V.,
Orlovskaya, N., Doped ceria-LaMeO3 (Me=Mn,
Fe, Co) nanocomposites: synthesis via mechanochemical
activation route and properties, in Generation, Storage
and Fuel Cells, edited by Anne Dillon, Charles Olk, Constantina
Filiou, Jim Ohi (Mater. Res. Soc. Symp. Proc. 885, Warrendale,
PA, 2006), 0885-A03-04.1.
- Sadykov,
V., Frolova-Borchert, Y., Alikina, G., Lukashevich, A.,
Bunina, R., Zabolotnaya, G., Mezentseva, N., Moroz, E.,
Rogov, V., Zaikovskii, V., Ishchenko, A., Uvarov, N.,
Zyryanov, V.V., Orlovskaya, N., One-pot synthesis of mixed
ionic-electronic conducting nanocomposites comprised of
fluorite-like and perovskite-like phases as catalytic
materials for SOFC, Nanoparticles and Nanostructures in
Sensors and Catalysis, edited by C.-J. Zhong, N. A. Kotov,
W. Daniell, F. P. Zamborini, (Mater. Res. Soc. Symp. Proc.
900E, Warrendale, PA, 2006), 0900-O10-08.1.
- Coratolo,
A., Orlovskaya, N., Johnson, C., Gemmen, R., Structural
evolution of La0.9Sr0.1Cr0.9Co0.1O3
thin films for SOFCs and catalysis, Nanoparticles and
Nanostructures in Sensors and Catalysis, edited by Chuan-Jian
Zhong, Nicholas A. Kotov, Wayne Daniell, Francis P. Zamborini
(Mater. Res. Soc. Symp. Proc. 900E, Warrendale, PA, 2006),
0900-O06-27.1.
- Orlovskaya,
N., Lugovy, M., Ko, F., S. Yarmolenko, J. Sankar, Kuebler,
J., SiC/SiCwoven fabric laminates: Design,
manufacturing, mechanical properties, Composites Part
B Engineering, 27, 6, 524-529, 2006.
- Orlovskaya, N., Lugovy, M., Kuebler, J.,
Yarmolenko, S., Sankar, J., Design of tough ceramic laminates
by residual stresses control, Chapter 7 in: Ceramic Matrix
Composites: Microstructure/Property Relationship, editor
I.M. Low, Woodhead Publishing Ltd, Cambridge, pp. 178-215,
2006.
- Coratolo,
A., Orlovskaya, N., Lugovy, M. Slyunayaev, V., Dub., S.,
Johnson, C., Gemmen, R., Nanoindentation of LaCrO3
thin film, J. Mat. Sci., 41, 10, 3105-3111, 2006.
- Johnson, C., Gemmen, R., Poston, J., Schaeffer,
C., Orlovskaya, N., Fegely, L., Rawn, C., Perovskite based
protective coatings for Solid Oxide Fuel Cell metallic
interconnects, Proceeding of Ninth International Meeting
of Solid Oxide Fuel Cells, Quebec City, 1842-1850, 2005.
- Orlovskaya, N., Nicholls, A., Yarmolenko,
S., Sankar, J., Johnson, C., Gemmen, R., Microstructural
characterization of La-Cr-O thin films deposited by magnetron
sputtering on the stainless steel interconnect materials
for SOFC application, in a book "Fuel Cells: State and
Prospectives ", Eds. Sammes, N., Vasylyev, O., Kluwer
Academic Publishers, 355-371, 2005.
- Orlovskaya, N., Steinmetz,
D., Yarmolenko, S., Pai, D., Sankar, J., Goodenough, J.,
Detection of temperature and stress induced modifications
of LaCoO3 by micro-Raman spectroscopy, Phys.
Rev. B, 72, 014122-1-7, 2005.
- Orlovskaya,
N., Lugovy, M., Subbotin, V., Radchenko, O., Adams, J.,
Chheda, M., Shih, J., Sankar, J., Yarmolenko, S., Robust
design and manufacturing of ceramic laminates with controlled
thermal residual stresses for enhanced toughness, J. Mat.
Sci., 40, 5483-5490, 2005.
- Orlovskaya,
N., Kuebler, J., Subbotin, V., Lugovy, Design of Si3N4
-based ceramic laminates by residual stresses, J. Mat.
Sci., 40, 5443-5450, 2005.
- Blugan, G., Dobedoe, R., Gee, I., Orlovskaya,
N., Kuebler, J., Failure behavior of high toughness multilayer
Si3N4 and Si3N4-TiN
based laminates, Key Engineering Materials, 290, 175-182,
2005.
- Lugovy,
M., Sljunyaev, V., Orlovskaya, N., Blugan, G., Kuebler,
J., Lewis, M., Apparent fracture toughness of Si3N4
based laminates with residual compressive or tensile stresses
in surface layers, Acta Mater., 53, 289-296, 2005.
- Orlovskaya,
N., Coratolo, A., Johnson, C., Gemmen, R., Characterization
of LaCrO3 perovskite coating deposited by magnetron sputtering
on an iron based chromium containing alloy, J. Am. Ceram.
Soc., 87, 10, 1981-1987, 2004.
- Mixed Ionic Electronic Conducting Perovskites
for Advanced Energy Systems, Eds. N. Orlovskaya, N. Browning,
Kluwer Academic Publishers, pp.315, 2004.
- Orlovskaya, N., Steinmetz, D., Raman diagnostics
of LaCoO3 based perovskites, in book "Mixed
ionic electronic conducting perovskites for advanced energy
systems", Eds. Orlovskaya, N., and Browning, N., Kluwer
Academic Publishers, p. 37-49, 2004.
- Wiik, K., Fossdal, A., Sagdahl, L., Lein,
H., Menon, M., Faaland, S., Waernhus, I., Orlovskaya,
N., Einarsrud, M.-A., Grande, T., LaFeO3 and
LaCoO3 Based Perovskites: Preparation and Properties
of Dense Oxygen Permeable Membranes, in book "Mixed ionic
electronic conducting perovskites for advanced energy
systems", Eds. Orlovskaya, N., and Browning, N., Kluwer
Academic Publishers, p.72-82, 2004.
- Blugan, G., Orlovskaya, N., Lewis, M., Kuebler,
J., Multilayer silicon nitride laminates exhibiting high
fracture toughness and crack deflection, Key Engineering
Materials, 280-283, 1863-1868, 2004.
- Lugovy,
M., Slyunyayev, V., Subbotin, V., Orlovskaya, N., Gogotsi,
G., Crack arrest in Si3N4-based
layered composites with residual stress, Composites Science
and Technology, 64, 13-14, 1947-1957, 2004.
- Johnson, C.,
Gemmen, R., Orlovskaya, N., Nano-structured self-assembled
LaCrO3 thin film deposited by RF magnetron sputtering
on a stainless steel interconnect material, Composites,
Part B: Engineering, 35, 2, 167-172, 2004.
- Orlovskaya,
N., Browning, N., Nicholls, A., Ferroelasticity in mixed
conducting LaCoO3 based perovskites: A ferroelastic
phase transition, Acta. Mater., 51, 17, 5063-5071, 2003.
- Orlovskaya, N., Adams, J., Chheda, M., Shih,
J., Yarmolenko, S., Sankar, J., Lugovy, M., Subbotin,
V., Boron carbide - silicon carbide laminate ceramics
for ballistic protection, Proceedings of IMECE-03, 2003
ASME International Mechanical Engineering Congress &
Exposition, Washington, D.C., November 16-21, 2003.
- Orlovskaya, N., Lugovy, M., Subbotin, V.,
Radchenko, O., Adams, J., Chheda, M., Shih, J., Sankar,
J., Yarmolenko, S., Design and manufacturing B4C-SiC
layered ceramics for armor applications, in the book "Ceramic
Armor and Armor Systems" (Ceramic Transactions, Volume
151) 2003, pp. 59-70.
- Lugovy,
M., Orlovskaya, N., Slyunayev, V., Gogotsi, G., Kuebler,
J., Sanchez-Herencia, A., Crack bifurcation features in
laminar specimens with fixed total thickness, Composite
Science and Technology, 62, 819-830, 2002.
- Orlovskaya, N.,
Gogotsi, Y., Reece, M., Cheng, B., Gibson, I., Ferroelasticity
and hysteresis in LaCoO3 based perovskites,
Acta Mater., 50, 4, 715-723, 2002.
- Orlovskaya,
N., Kuebler, J., Subbotin, V., Tough ceramic laminates
by design of residual stresses, Advanced Fibers, Plastics,
Laminates and Composites, edited by F. T. Wallenberger,
N. E. Weston, R. Ford, R. P. Wool, K. Chawla, (Mater.
Res. Soc. Symp. Proc. 702, Warrendale, PA, 2002), U8.7.1.
- Orlovskaya, N., Gogotsi, Y., Residual stresses
in Si3N4 based ceramic laminates,
Key Engineering Materials, 206-213, 1025-1028, 2002.
- Orlovskaya, N., Gogotsi, Y., Nicholls, A.,
Twins in LaCoO3 based ferroic perovskites,
Proceedings of 7th Int. Symp. On Solid Oxide Fuel Cells,
Eds. Yokokawa, H., Singhal, S.C., 2001-16, 624-632, 2001.
- Orlovskaya, N., Ge, D., Nicholls, A., In-Situ
TEM Study of High Temperature Stability of LaCoO3
Based Ferroic Perovskites, Key Engineering Materials,
206-213, 2001.
- Kleveland, K., Orlovskaya, N., Grande, T.,
Moe, A.-M., Einarsrud, M.-A., Breder, K., Gogotsi, G.,
Non-linear behavior of LaCoO3 perovskites,
J. Am. Ceram. Soc., 84, 9, 2029-2033, 2001.
- Lugovy, M., Orlovskaya, N., Berroth, K.,
Kuebler, J., Analysis of layered composite with crack
deflection controlled by layer thickness, Proceedings
of the NATO ASI "Functional gradient materials and surface
layers prepared by fine particle technology", Kiev, Ukraine,
18-28 June, 2000, Ed. By M.-I. Baraton and I. Uvarova,
NATO Science Series, II, Mathematics, Physics and Chemistry,
16, Kluwer Academic Publishers, 273-280, 2001.
- Orlovskaya,
N., Kleveland, K., Grande, T., Einarsrud, M.-A., Mechanical
properties of LaCoO3-based ceramics, J. Eur.
Ceram. Soc., 20, 51-56, 2000.
- Orlovskaya,
N., Gonzalez, N., Nonelastic ferroelastic behavior of
LaCoO3 based ceramics under contact loading,
J. Materials Processing and Manufacturing Science, 9,
53-63, 2000.
- Lugovy,
M., Orlovskaya, N., Berroth, K., Kuebler, J., Macrostructural
engineering of ceramic-matrix layered composites, Composite
Science and Technology, 59, 8, 1429-1437, 1999.
- Lugovy,
M., Orlovskaya, N., Berroth, K., Kuebler, J., Microstructural
Engineering of Ceramic-Matrix Layered Composites: Effect
of Grain Size Dispersion on Single-Phase Ceramic Strength,
Composite Science and Technology, 59, 2, 283-289, 1999.
- Yaroshenko, V., Orlovskaya, N., Einarsrud,
M.-A., Kovylayev, V., Processing of multilayered Si3N4-TiN
hot-pressed ceramic composites /Proceedings of NATO ARW
"Multilayered and fibre-reinforced composites: Problems
and Prospects", Kluwer, Dordrech, 285-295, 1998.
- Ostrovoj,
D., Orlovskaya, N., Kovylayev, V., Firstov, S., Mechanical
Properties of Toughened Al2O3-ZrO2-
TiN Ceramics, J. Europ. Ceram. Soc., 18, 381-388, 1998.
- Orlovskaya
N, Peterlik H., Marczewski M., Kromp K. The validity of
Weibull estimators - experimental verification, J. Mat.
Sci., 3, 978-983, 1997.
- Yaroshenko, V., Orlovskaya, N., Einarsrud,
M.-A., Berroth, K., Kovylayev, V., Laminar Si3N4-TiN
hot-pressed ceramic composites, Euro Ceramics 3, Key Engineering
Materials, 132-136, 2017-2020, 1997.
- Orlovskaya, N., Krivoshej, G., Babij, O.,
Ostrovoj, D., Effect of annealing on microstructure, phase
composition and failure of Al2O3-ZrO2
ceramics at room temperature, J. Mat. Sci. Let. , 3, 106-109,
1996.
- Orlovskaja,
N., Peterlik, H., Steinkellner, W., Kromp, K., Prediction
of strength of recrystallized siliconcarbide from pore
sized measurement. Part I - The bimodality of the distribution;
Journal of Materials Science 35 (2000) 699-705
- Peterlik, H., Orlovskaja, N., Steinkellner, W., Kromp, K., Prediction of strength of recrystallized siliconcarbide from pore sized measurement. Part II - The reliability of the prediction; Journal of Materials Science 35 (2000) 699-705
